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Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation - Nature Catalysis

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Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation - Nature Catalysis

Catalytic cross-coupling by transition metals has revolutionized the formation of carbon–carbon bonds in organic synthesis. However, the challenge of forming multiple alkyl–alkyl bonds in crowded environments remains largely unresolved. Here we report the regioselective functionalization of olefins with sp3-hybridized organohalides and organozinc reagents using a simple (terpyridine)iron catalyst.

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Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation - Nature Catalysis

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Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation - Nature Catalysis

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