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Desolvation of metal complexes to construct metal–organic framework glasses - Nature Synthesis

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Desolvation of metal complexes to construct metal–organic framework glasses - Nature Synthesis

Structural design is an important challenge in glassy materials, including metal–organic framework (MOF) glasses. The current approaches of thermal and mechanical vitrification are mainly limited to azolate and cyanide-based crystalline MOFs, as other MOF crystals usually decompose before melting or upon milling instead of forming stable glasses. Here we report a method for the preparation of MOF glasses by the 'desolvation' of solvated metal–ligand discrete complexes.

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Desolvation of metal complexes to construct metal–organic framework glasses - Nature Synthesis

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Desolvation of metal complexes to construct metal–organic framework glasses - Nature Synthesis

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