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Stereoretentive enantioconvergent reactions - Nature Chemistry

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Stereoretentive enantioconvergent reactions - Nature Chemistry

Enantioconvergent reactions are pre-eminent in contemporary asymmetric synthesis as they convert both enantiomers of a racemic starting material into a single enantioenriched product, thus avoiding the maximum 50% yield associated with resolutions. All currently known enantioconvergent processes necessitate the loss or partial loss of the racemic substrate's stereochemical information, thus limiting the potential substrate scope to molecules that contain labile stereogenic units.

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Stereoretentive enantioconvergent reactions - Nature Chemistry

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Stereoretentive enantioconvergent reactions - Nature Chemistry

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