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Methylation enables high-voltage ether electrolytes for lithium metal batteries - Nature Chemistry

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Methylation enables high-voltage ether electrolytes for lithium metal batteries - Nature Chemistry

Ether-based electrolytes are desired for lithium metal batteries owing to their low reduction potentials; however, they suffer from low anodic stability. Strategic methylation of ether solvents is shown to extend their electrochemical stability and facilitate the formation of LiF-rich interphases, enabling high-voltage lithium metal batteries while avoiding the use of fluorinated solvents.

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Methylation enables high-voltage ether electrolytes for lithium metal batteries - Nature Chemistry

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Methylation enables high-voltage ether electrolytes for lithium metal batteries - Nature Chemistry

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