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Cage escape governs photoredox reaction rates and quantum yields - Nature Chemistry

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Cage escape governs photoredox reaction rates and quantum yields - Nature Chemistry

Photoredox catalysis relies on light-induced electron transfer leading to a radical pair comprising an oxidized donor and a reduced acceptor in a solvent cage. For productive onward reaction to occur, the oxidized donor and the reduced acceptor must escape from that solvent cage before they undergo spontaneous reverse electron transfer.

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Cage escape governs photoredox reaction rates and quantum yields - Nature Chemistry

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Cage escape governs photoredox reaction rates and quantum yields - Nature Chemistry

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