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Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds - Nature Catalysis

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Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds - Nature Catalysis

Constructive functionalization of unstrained aryl–aryl bonds has been a fundamental challenge in organic synthesis due to the inertness of these bonds. Here we report a split cross-coupling strategy that allows twofold arylation with diverse aryl iodides through cleaving unstrained aryl–aryl bonds of common 2,2′-biphenols. The reaction is catalysed by a rhodium complex and promoted by a removable phosphinite directing group and an organic reductant such as tetrakis(dimethylamino)ethylene.

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Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds - Nature Catalysis

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