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Metal-free organocatalytic S-formylation of thiols using CO2 - Nature Catalysis

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Metal-free organocatalytic S-formylation of thiols using CO2 - Nature Catalysis

S-formylation of thiols is achieved via an enzymatic process catalysed by formate dehydrogenase enzyme that fixes CO2 onto substrates, which plays a crucial role in regulating important biological pathways in living organisms. The achievement of this reactivity through a chemical approach could also be advantageous, which would allow the fixation of CO2 on a diverse range of thiols.

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Metal-free organocatalytic S-formylation of thiols using CO2 - Nature Catalysis

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Metal-free organocatalytic S-formylation of thiols using CO2 - Nature Catalysis

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