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Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer - Nature Catalysis

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Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer - Nature Catalysis

The photochemical [2+2] cycloaddition of styrenes provides a frequently used route for the synthesis of multi-substituted cyclobutanes. Despite the extensive studies in noble-metal and organo-photocatalysis, developing sustainable cycloaddition methods with copper photosensitizers is still in its infancy, largely owing to their low reactivity and photostability.

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Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer - Nature Catalysis

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Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer - Nature Catalysis

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