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Site-selective episulfonium formation on protein surfaces - Nature Chemistry

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Site-selective episulfonium formation on protein surfaces - Nature Chemistry

Covalent protein conjugation facilitates the study of biological processes and the synthesis of therapeutic biomacromolecules. A method that uses vinyl thianthrenium reagents for the site-selective formation of highly reactive episulfonium species on proteins is demonstrated. These in situ-formed intermediates react with diverse nucleophiles, providing access to protein conjugates in one step without purification.

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Site-selective episulfonium formation on protein surfaces - Nature Chemistry

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Site-selective episulfonium formation on protein surfaces - Nature Chemistry

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