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Stereodivergent 1,3-difunctionalization of alkenes by charge relocation - Nature

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Stereodivergent 1,3-difunctionalization of alkenes by charge relocation - Nature

Alkenes are indispensable feedstocks in chemistry. Functionalization at both carbons of the alkene—1,2-difunctionalization—is part of chemistry curricula worldwide1. Although difunctionalization at distal positions has been reported2–4, it typically relies on designer substrates featuring directing groups and/or stabilizing features, all of which determine the ultimate site of bond formation5–7.

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Stereodivergent 1,3-difunctionalization of alkenes by charge relocation - Nature

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Stereodivergent 1,3-difunctionalization of alkenes by charge relocation - Nature

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