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Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center - Nature Communications

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Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center - Nature Communications

We describe nonmetal adducts of the phosphorus center of terminal phosphinidene complexes using classical C- and N-ligands from metal coordination chemistry. The nature of the L-P bond has been analyzed by various theoretical methods including a refined method on the variation of the Laplacian of electron density ∇2ρ along the L-P bond path.

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Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center - Nature Communications

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Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center - Nature Communications

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