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An electrochemical approach for designing thermochemical bimetallic nitrate hydrogenation catalysts - Nature Catalysis
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Classically, catalytic promotion in bimetallic catalysts has been ascribed to atomic-scale cooperativity between metal constituents. For catalytic reactions that could involve charge transfer, electron and ion flow may engender bimetallic promotion without atomic-level connectivity. Here we examine this hypothesis in the context of nitrate hydrogenation, a reaction catalysed almost exclusively by bimetallic catalysts.
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