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A photocatalytic method for the regioselective carboxylation of azine C–H bonds using CO2 - Nature Synthesis
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The visible-light-driven thiolate-catalysed carboxylation of C(sp2)–H bonds in azines using CO2 is demonstrated. This procedure can be applied to various azine substrates to obtain a range of N-heteroaromatic carboxylic acids with different functionalities, including bioactive molecules and carboxylated N-ligands.
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