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Interlocked polyynes towards stable carbynes - Nature Chemistry

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Interlocked polyynes towards stable carbynes - Nature Chemistry

Interlocking unstable motifs is a useful way to enhance their stability through shielding protection. Now, stable interlocked polyynes bearing several macrocycles have been prepared, including a [5]rotaxane having 34 contiguous alkynes with properties similar to those of carbyne.

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Interlocked polyynes towards stable carbynes - Nature Chemistry

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Interlocked polyynes towards stable carbynes - Nature Chemistry

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