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Catalytic asymmetric cationic shifts of aliphatic hydrocarbons - Nature

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Catalytic asymmetric cationic shifts of aliphatic hydrocarbons - Nature

Asymmetric catalysis is an advanced area of chemical synthesis, but the handling of abundantly available, purely aliphatic hydrocarbons has proven to be challenging. Typically, heteroatoms or aromatic substructures are required in the substrates and reagents to facilitate an efficient interaction with the chiral catalyst. Confined acids have recently been introduced as tools for homogenous asymmetric catalysis, specifically to enable the processing of small unbiased substrates1.

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Catalytic asymmetric cationic shifts of aliphatic hydrocarbons - Nature

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Catalytic asymmetric cationic shifts of aliphatic hydrocarbons - Nature

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