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Dynamic molecular pockets on one-dimensional channels for splitting ethylene from C2–C4 alkynes - Nature Chemical Engineering

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Dynamic molecular pockets on one-dimensional channels for splitting ethylene from C2–C4 alkynes - Nature Chemical Engineering

Molecular sieving adsorbents can offer maximum adsorption selectivity with respect to molecular sizes, yet it is still challenging to discriminate middle-sized molecules from a mixture of three or more components. Here we report a metal–organic framework (JNU-3a) with dynamic molecular pockets along one-dimensional channels, enabling the one-step removal of ethylene (C2H4) from mixtures with C2–C4 alkynes in a single adsorption step regardless of their molecular sizes.

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Dynamic molecular pockets on one-dimensional channels for splitting ethylene from C2–C4 alkynes - Nature Chemical Engineering

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Dynamic molecular pockets on one-dimensional channels for splitting ethylene from C2–C4 alkynes - Nature Chemical Engineering

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