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Perpendicular state of stilbene unveiled with ultrafast Raman spectroscopy - Nature Chemistry

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Perpendicular state of stilbene unveiled with ultrafast Raman spectroscopy - Nature Chemistry

Trans–cis photoisomerization is a fundamental photochemical reaction that is thought to proceed through an intermediate with a perpendicular conformation. However, unambiguous identification of this state has proved challenging. The combination of state-of-the-art ultrafast spectroscopy and quantum chemical calculations now provides evidence for its structural observation in stilbene photoisomerization.

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Perpendicular state of stilbene unveiled with ultrafast Raman spectroscopy - Nature Chemistry

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Perpendicular state of stilbene unveiled with ultrafast Raman spectroscopy - Nature Chemistry

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