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Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation - Nature Chemistry

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Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation - Nature Chemistry

Cysteine conjugation is an important tool in protein research and relies on fast, mild and chemoselective reactions. Cysteinyl thiols can either be modified with prefunctionalized electrophiles, or converted into electrophiles themselves for functionalization with selected nucleophiles in an independent step.

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Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation - Nature Chemistry

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Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation - Nature Chemistry

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