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Biomimetic tail-to-head terpene cyclizations using the resorcin[4]arene capsule catalyst - Nature Protocols

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Biomimetic tail-to-head terpene cyclizations using the resorcin[4]arene capsule catalyst - Nature Protocols

The tail-to-head terpene (THT) cyclization is a biochemical process that gives rise to many terpene natural product skeletons encountered in nature. Historically, it has been difficult to achieve THT synthetically without using an enzyme. In this protocol, a hexameric resorcin[4]arene capsule acts as an artificial enzyme mimic to carry out biomimetic THT cyclizations and related carbocationic rearrangements.

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Biomimetic tail-to-head terpene cyclizations using the resorcin[4]arene capsule catalyst - Nature Protocols

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Biomimetic tail-to-head terpene cyclizations using the resorcin[4]arene capsule catalyst - Nature Protocols

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