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Ultra-fast supercritically solvothermal polymerization for large single-crystalline covalent organic frameworks - Nature Protocols
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Crystalline polymer materials, e.g., hyper-crosslinked polystyrene, conjugate microporous polymers and covalent organic frameworks, are used as catalyst carriers, organic electronic devices and molecular sieves. Their properties and applications are highly dependent on their crystallinity. An efficient polymerization strategy for the rapid preparation of highly or single-crystalline materials is beneficial not only to structure–property studies but also to practical applications.
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