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Masked alkynes for synthesis of threaded carbon chains - Nature Chemistry

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Masked alkynes for synthesis of threaded carbon chains - Nature Chemistry

Polyynes are chains of sp1 carbon atoms with alternating single and triple bonds. As they become longer, they evolve towards carbyne, the 1D allotrope of carbon, and they become increasingly unstable. It has been anticipated that long polyynes could be stabilized by supramolecular encapsulation, by threading them through macrocycles to form polyrotaxanes—but, until now, polyyne polyrotaxanes with many threaded macrocycles have been synthetically inaccessible.

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Masked alkynes for synthesis of threaded carbon chains - Nature Chemistry

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Masked alkynes for synthesis of threaded carbon chains - Nature Chemistry

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