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Remote stereocontrol with azaarenes via enzymatic hydrogen atom transfer - Nature Chemistry

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Remote stereocontrol with azaarenes via enzymatic hydrogen atom transfer - Nature Chemistry

Strategies for achieving asymmetric catalysis with azaarenes have traditionally fallen short of accomplishing remote stereocontrol, which would greatly enhance accessibility to distinct azaarenes with remote chiral centres. The primary obstacle to achieving superior enantioselectivity for remote stereocontrol has been the inherent rigidity of the azaarene ring structure.

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Remote stereocontrol with azaarenes via enzymatic hydrogen atom transfer - Nature Chemistry

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Remote stereocontrol with azaarenes via enzymatic hydrogen atom transfer - Nature Chemistry

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