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Modular and diverse synthesis of amino acids via asymmetric decarboxylative protonation of aminomalonic acids - Nature Chemistry

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Modular and diverse synthesis of amino acids via asymmetric decarboxylative protonation of aminomalonic acids - Nature Chemistry

Stereoselective protonation is a challenge in asymmetric catalysis. The small size and high rate of transfer of protons mean that face-selective delivery to planar intermediates is hard to control, but it can unlock previously obscure asymmetric transformations. Particularly, when coupled with a preceding decarboxylation, enantioselective protonation can convert the abundant acid feedstocks into structurally diverse chiral molecules.

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Modular and diverse synthesis of amino acids via asymmetric decarboxylative protonation of aminomalonic acids - Nature Chemistry

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Modular and diverse synthesis of amino acids via asymmetric decarboxylative protonation of aminomalonic acids - Nature Chemistry

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