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Discovery and synthesis of atropisomerically chiral acyl-substituted stable vinyl sulfoxonium ylides - Nature Chemistry

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Discovery and synthesis of atropisomerically chiral acyl-substituted stable vinyl sulfoxonium ylides - Nature Chemistry

Atropisomerism is a type of conformational chirality that plays a critical role in various fields of chemistry, including synthetic, medicinal and material chemistry, and its impact has been widely recognized. Although chiral atropisomerism in rotationally restricted aryl–aryl bonds has garnered substantial interest and led to important discoveries in chiral catalysts and drug development, the exploration of non-aryl atropisomers has fallen behind.

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Discovery and synthesis of atropisomerically chiral acyl-substituted stable vinyl sulfoxonium ylides - Nature Chemistry

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Discovery and synthesis of atropisomerically chiral acyl-substituted stable vinyl sulfoxonium ylides - Nature Chemistry

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