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Generation and reactivity of unsymmetrical strained heterocyclic allenes - Nature Synthesis

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Generation and reactivity of unsymmetrical strained heterocyclic allenes - Nature Synthesis

Strained cyclic allenes are short-lived intermediates that confine a functional group with a preferred linear geometry, an allene, into a small ring, inducing strain-driven reactivity. Nitrogen-containing variants, or azacyclic allenes, have proved valuable for the assembly of complex nitrogen-containing compounds. Whereas 3,4-azacyclic allenes, which bear a symmetrical core, have been the focus of multiple studies, their unsymmetrical 2,3-azacyclic counterparts have remained underexplored.

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Generation and reactivity of unsymmetrical strained heterocyclic allenes - Nature Synthesis

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