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Defying thermodynamics to synthetize hydrazine - Nature Catalysis

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Defying thermodynamics to synthetize hydrazine - Nature Catalysis

Selective electrochemical oxidation of ammonia provides an ideal pathway to synthesize hydrazine, but this process is outcompeted by a more favourable overoxidation to N2. A molecular ruthenium catalyst has now flipped the script, circumventing the thermodynamic challenges to selectively generate hydrazine.

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Defying thermodynamics to synthetize hydrazine - Nature Catalysis

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Defying thermodynamics to synthetize hydrazine - Nature Catalysis

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