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Face-directed assembly of tailored isoreticular MOFs using centring structure-directing agents - Nature Synthesis

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Face-directed assembly of tailored isoreticular MOFs using centring structure-directing agents - Nature Synthesis

Building blocks with low connectivity and no embedded directionality are prone to polymorphism, as demonstrated by the diversity of 4-connected zeolitic nets (>250). As a result, their deployment for design in reticular and isoreticular chemistries remains a challenge. However, the ability to control geometrical peculiarities offers potential to deviate from the assembly of default structures.

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Face-directed assembly of tailored isoreticular MOFs using centring structure-directing agents - Nature Synthesis

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Face-directed assembly of tailored isoreticular MOFs using centring structure-directing agents - Nature Synthesis

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