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The role of aromaticity in the cyclization and polymerization of alkyne-substituted porphyrins on Au(111) - Nature Chemistry

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The role of aromaticity in the cyclization and polymerization of alkyne-substituted porphyrins on Au(111) - Nature Chemistry

Aromaticity is an established and widely used concept for the prediction of the reactivity of organic molecules. However, its role remains largely unexplored in on-surface chemistry, where the interaction with the substrate can alter the electronic and geometric structure of the adsorbates. Here we investigate how aromaticity affects the reactivity of alkyne-substituted porphyrin molecules in cyclization and coupling reactions on a Au(111) surface.

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The role of aromaticity in the cyclization and polymerization of alkyne-substituted porphyrins on Au(111) - Nature Chemistry

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The role of aromaticity in the cyclization and polymerization of alkyne-substituted porphyrins on Au(111) - Nature Chemistry

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