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Back-to-back cycloadditions in nature - Nature Chemistry

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Back-to-back cycloadditions in nature - Nature Chemistry

Tandem cycloaddition reactions have significant applications in organic synthetic chemistry. Now, two enzymes are shown to catalyse tandem hetero-Diels–Alder reactions with a synergistic interplay between a calcium cofactor and N-glycan post-translational modifications during the biosynthesis of bistropolone-sesquiterpene secondary metabolites.

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Back-to-back cycloadditions in nature - Nature Chemistry

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Back-to-back cycloadditions in nature - Nature Chemistry

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