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Route to complex colloidal crystals through entropy compartmentalization - Nature Chemistry

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Route to complex colloidal crystals through entropy compartmentalization - Nature Chemistry

Colloidal clathrate crystals self-assembled from hard polyhedral shapes in computer simulations are stabilized by entropy compartmentalization, whereby hosts and guests contribute unequally to the entropy. This creative solution to satisfying the laws of thermodynamics suggests new ways to make colloidal crystals with

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Route to complex colloidal crystals through entropy compartmentalization - Nature Chemistry

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Route to complex colloidal crystals through entropy compartmentalization - Nature Chemistry

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