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Tetramethylphosphinane as a new secondary phosphine synthon - Communications Chemistry

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Tetramethylphosphinane as a new secondary phosphine synthon - Communications Chemistry

Secondary phosphines are important building blocks in organic chemistry as their reactive P—H bond enables construction of more elaborate molecules. In particular, they can be used to construct tertiary phosphines that have widespread applications as organocatalysts, and as ligands in metal-complex catalysis. We report here a practical synthesis of the bulky secondary phosphine synthon 2,2,6,6-tetramethylphosphinane (TMPhos).

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Tetramethylphosphinane as a new secondary phosphine synthon - Communications Chemistry

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Tetramethylphosphinane as a new secondary phosphine synthon - Communications Chemistry

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