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Structure of AlkB–AlkG shows details of alkane terminal C–H selectivity and functionalization - Nature Structural & Molecular Biology

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Structure of AlkB–AlkG shows details of alkane terminal C–H selectivity and functionalization - Nature Structural & Molecular Biology

The cryo-EM structure of a natural AlkB–AlkG fusion from Fontimonas thermophila reveals the mechanistic basis for its selectivity towards, and functionalization of, alkane terminal C–H groups. AlkB contains an alkane entry tunnel and a diiron active site, and AlkG docks through electrostatic interactions and transfers electrons to the diiron center for catalysis.

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Structure of AlkB–AlkG shows details of alkane terminal C–H selectivity and functionalization - Nature Structural & Molecular Biology

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Structure of AlkB–AlkG shows details of alkane terminal C–H selectivity and functionalization - Nature Structural & Molecular Biology

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