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Isolation, bonding and reactivity of a monomeric stibine oxide - Nature Chemistry

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Isolation, bonding and reactivity of a monomeric stibine oxide - Nature Chemistry

In contrast to phosphine oxides and arsine oxides, which are common and exist as stable monomeric species featuring the corresponding pnictoryl functional group (Pn=O/Pn+–O−; Pn = P, As), stibine oxides are generally polymeric, and the properties of the unperturbed stiboryl group (Sb=O/Sb+–O−) remain unexplored. We now report the isolation of the monomeric stibine oxide, Dipp3SbO (where Dipp = 2,6-diisopropylphenyl).

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Isolation, bonding and reactivity of a monomeric stibine oxide - Nature Chemistry

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Isolation, bonding and reactivity of a monomeric stibine oxide - Nature Chemistry

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