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Alkyne synthesis through coupling of gem-diborylalkanes with carboxylic acid esters - Nature Synthesis
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Alkynes are fundamental molecular building blocks of great importance in synthetic chemistry and materials science. The efficient construction of alkynyl functionality from widely accessible functional groups is therefore highly valuable. Here we report the development of a modular synthesis of alkynes through reaction of carboxylic esters with lithiated gem-diborylalkanes and aryl triflimides.
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