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Making molecular nanotubes by cross-linking stackable rings - Nature Synthesis
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Discrete chiral nanotubes have been synthesized with high efficiency by connecting rim-desymmetrized macrocycles through dynamic covalent linkages. These 2-nm long and 4.7-Å wide helical covalent organic pillars, resolved by chromatography and characterized by X-ray crystallography, show strong binding affinities for linear guest molecules with complementary lengths and electronic densities.
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