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Selective cycloadditions - Nature Chemistry

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Selective cycloadditions - Nature Chemistry

2+2-cycloaddition reactions have long been considered key transformations in the biosynthesis of cyclobutane-containing natural products, but enzymes for these reactions have not yet been identified. Now, a 2+2 cyclase has been discovered, characterized and bioengineered to catalyse cycloadditions with different selectivity.

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Selective cycloadditions - Nature Chemistry

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