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A cyclase that catalyses competing 2 + 2 and 4 + 2 cycloadditions - Nature Chemistry

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A cyclase that catalyses competing 2 + 2 and 4 + 2 cycloadditions - Nature Chemistry

Cycloaddition reactions are among the most widely used reactions in chemical synthesis. Nature achieves these cyclization reactions with a variety of enzymes, including Diels–Alderases that catalyse concerted 4 + 2 cycloadditions, but biosynthetic enzymes with 2 + 2 cyclase activity have yet to be discovered.

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A cyclase that catalyses competing 2 + 2 and 4 + 2 cycloadditions - Nature Chemistry

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A cyclase that catalyses competing 2 + 2 and 4 + 2 cycloadditions - Nature Chemistry

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