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Chemodivergent C(sp3)–H and C(sp2)–H cyanomethylation using engineered carbene transferases - Nature Catalysis

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Chemodivergent C(sp3)–H and C(sp2)–H cyanomethylation using engineered carbene transferases - Nature Catalysis

The ubiquity of C–H bonds presents an opportunity to efficiently elaborate and build complexity in organic molecules. Methods for selective functionalization, however, must differentiate among multiple, chemically similar C–H bonds: enzymes are attractive because they can be finely tuned using directed evolution to achieve divergent reaction outcomes.

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Chemodivergent C(sp3)–H and C(sp2)–H cyanomethylation using engineered carbene transferases - Nature Catalysis

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Chemodivergent C(sp3)–H and C(sp2)–H cyanomethylation using engineered carbene transferases - Nature Catalysis

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