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Reactive trans-dimetallated alkenes from alkynes - Nature Synthesis

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Reactive trans-dimetallated alkenes from alkynes - Nature Synthesis

Reductive anti-1,2-dimetallation of alkynes proceeds through the use of sodium dispersion as a reducing agent and an organomagnesium or organoaluminum halide as a reduction-resistant electrophile. The reaction stereoselectively generates trans-1,2-dimagnesio- or 1,2-dialuminoalkenes, which show useful reactivity.

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Reactive trans-dimetallated alkenes from alkynes - Nature Synthesis

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Reactive trans-dimetallated alkenes from alkynes - Nature Synthesis

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