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Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer - Nature Communications

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Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer - Nature Communications

Construction of C-N bond continues to be one part of the most significant goals in organic chemistry because of the universal applications of amines in pharmaceuticals, materials and agrochemicals. However, E2 elimination through classic SN2 substitution of alkyl halides lead to generation of alkenes as major side-products. Thus, formation of a challenging C(sp3)-N bond especially on tertiary carbon center remains highly desirable.

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Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer - Nature Communications

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Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer - Nature Communications

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