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Mild and metal-free Birch-type hydrogenation of (hetero)arenes with boron carbonitride in water - Nature Catalysis

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Mild and metal-free Birch-type hydrogenation of (hetero)arenes with boron carbonitride in water - Nature Catalysis

The direct reduction of inert planar arenes and heteroarenes with visible light remains rarely explored, as the energy of one visible-light photon is unable to overcome the stabilization of aromatics. Here we report a system based on boron carbonitride semiconductor, which can reduce arenes and heteroarenes in water under blue light irradiation. The system features the advantage of low-cost, high-efficiency, facile separation, benign environmental profile and broad substituent tolerance.

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Mild and metal-free Birch-type hydrogenation of (hetero)arenes with boron carbonitride in water - Nature Catalysis

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Mild and metal-free Birch-type hydrogenation of (hetero)arenes with boron carbonitride in water - Nature Catalysis

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