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Ring contraction of metallacyclobutadiene to metallacyclopropene driven by π- and σ-aromaticity relay - Nature Synthesis

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Ring contraction of metallacyclobutadiene to metallacyclopropene driven by π- and σ-aromaticity relay - Nature Synthesis

π-Aromaticity is an important driving force in directing the synthesis of aromatic compounds; in contrast, reactions induced by σ-aromaticity are uncommon. Here we report a strategy based on π- and σ-aromaticity relays to realize the structurally defined ring contraction of metallacyclobutadiene to metallacyclopropene.

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Ring contraction of metallacyclobutadiene to metallacyclopropene driven by π- and σ-aromaticity relay - Nature Synthesis

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Ring contraction of metallacyclobutadiene to metallacyclopropene driven by π- and σ-aromaticity relay - Nature Synthesis

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Unlocking the Power of Knowledge
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