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Chemoselective carbene insertion into the N−H bonds of NH3·H2O - Nature Communications

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Chemoselective carbene insertion into the N−H bonds of NH3·H2O - Nature Communications

The conversion of inexpensive aqueous ammonia (NH3·H2O) into value-added primary amines by N−H insertion persists as a longstanding challenge in chemistry because of the tendency of Lewis basic ammonia (NH3) to bind and inhibit metal catalysts. Herein, we report a chemoselective carbene N−H insertion of NH3·H2O using a TpBr3Ag-catalyzed two-phase system.

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Chemoselective carbene insertion into the N−H bonds of NH3·H2O - Nature Communications

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Chemoselective carbene insertion into the N−H bonds of NH3·H2O - Nature Communications

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