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Energy transfer-enabled unsymmetrical diamination using bifunctional nitrogen-radical precursors - Nature Catalysis

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Energy transfer-enabled unsymmetrical diamination using bifunctional nitrogen-radical precursors - Nature Catalysis

Vicinal diamines, especially unsymmetrical ones, are among the most common structural motifs in biologically active molecules, natural products and pharmaceuticals. While the catalytic diamination of carbon–carbon double bonds provides rapid access to diamines, these reactions are often limited to installation of undifferentiated amino functionalities through transition metals or hypervalent iodine reagent catalysis.

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Energy transfer-enabled unsymmetrical diamination using bifunctional nitrogen-radical precursors - Nature Catalysis

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Energy transfer-enabled unsymmetrical diamination using bifunctional nitrogen-radical precursors - Nature Catalysis

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