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A photoswitchable catalyst for the enantiodivergent epoxidation of alkenes - Nature Synthesis

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A photoswitchable catalyst for the enantiodivergent epoxidation of alkenes - Nature Synthesis

Coordination of a photoswitchable chiral phosphate ligand to an achiral manganese(iii)-salen complex yields a catalyst that can produce either enantiomer of an epoxide from a single alkene substrate. This enantiodivergent catalysis is governed by the transfer of the chirality of the phosphate ligand to the manganese(iii)-salen complex.

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A photoswitchable catalyst for the enantiodivergent epoxidation of alkenes - Nature Synthesis

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A photoswitchable catalyst for the enantiodivergent epoxidation of alkenes - Nature Synthesis

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